Hans, with all due respect (i.e. none at all..!), this is nonsense. How on earth is b/g a different outcome to g/b when you are not worried about the order...?
I was following with HKFC, but you've torn my world asunder here. You're right, at least I think so. Girl/boy and boy/girl are of course identical if you don't care about which is the older sibling.
So you do start with:
1. Boy/boy
2. Boy/girl
3. Girl/boy
4. Girl/girl
And you have a roughly 25% chance of each. By stating one of them is a boy you eliminate 4, and as you don't care about which sibling is which you combine 2 and 3 down to a single option, leaving you with a simple 50/50 chance.
Now does the order matter? If you were to say "The older sibling is a boy" then you can again eliminate option 4, and while you can't combine 2 and 3 you can eliminate 3 because the older sibling (the first one) is a girl. So you're still left with 50/50.