As 2 of my other faves have already been nabbed by NSCers with impeccable taste in music (The Clash's 'Complete Control' and 'White Man in Hammersmith Palais), I'll choose this
If I'd been allowed another choice, it would have been Pulp's 'Common People'
Beach Boys - God Only Knows
Not at all my usual style of music to listen to, and released over a decade before I was, but c'mon:
https://www.youtube.com/watch?v=4qoymGCDYzU
40 years on, I still get goose bumps when I hear this.
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Sounds as great today as it did 46 years ago