D
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The expansion vessel won’t be leaking as such, it will be the diaphragm inside the expansion that splits. Your plumber will be able to check this by opening the Schrader valve and testing to see if there’s water in there.
Regards the pipe under the floor, if it’s protected it should be ok, it’s when it’s unprotected the cement in the screed attacks the copper and pinholes it. How long has the copper been in the floor?
You can sometimes detect a leak on a heating system with a thermal camera, if you haven’t got one, order one, have a look, then send it back to get your money back.
I will check out valve, what pressure should this diaphragmm be set to?
The pipe was put in grey pipe insulation and sunk into the concreate 15 years ago.
Divining rods won't work then.